Average the points vertically first, then use Smart Guides to align them to the rectangle. How would Illustrator know which segment (vertical or horizontal) of the rectangle you wanted to align the points to in only one step?
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                                         Average the points vertically first, then use Smart Guides to align them to the rectangle. How would Illustrator know which segment (vertical or horizontal) of the rectangle you wanted to align the points to in only one step?